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SOLVED:(a) How many degrees of vibrational freedom does each of ClF3 and BF3 possess? The IR spectrum of ClF3 in an argon matrix exhibits six absorptions, whereas that of BF3 has only three. Explain why the spectra differ in this way. (b) Which of the following compounds are potentially explosive and must be treated with caution: ClO2, KClO4, KCl, Cl2 O6, Cl2 O Br2 O3, HF, CaF2, ClF3 and BrF3 ? State particular conditions under which explosions may occur. Are other serious hazards as
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